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Luxfer position concerning life extension of DOT CFFC carbon composite cylinders

For more than a decade, Luxfer has actively researched this matter and participated in detailed deliberations involving DOT, the Compressed Gas Association (CGA) and other cylinder manufacturers to obtain a service-life extension. However, DOT declined to approve life extension for these cylinders. Consequently, Luxfer decided not to pursue this effort further and to take a different approach to providing cylinders with longer service life.

Background

In 1996, DOT issued its CCFC-1 standard that established basic requirements for design, manufacture and performance of cylinders consisting of seamless aluminum liners over-wrapped with structural layers of filament-wound carbon fiber and epoxy composite material. At that time, DOT offered the possibility of extending the 15-year service life of such cylinders "up to a total service life of 30 years." To obtain an extension, a cylinder manufacturer was required to submit for DOT approval a "Service Life Extension Plan" that would meet certain criteria. Soon after CCFC-1 was issued, Luxfer and other U.S. cylinder manufacturers individually submitted such life-extension plans to DOT. However, DOT accepted none of these plans and declined to extend cylinder service life.

In response, cylinder manufacturers attempted an industry-wide approach to obtain DOT approval under the auspices of a special CGA task group, but the service life was not extended.

Luxfer's longer-life composite cylinder

In 2006, Luxfer began developing a new, more robust cylinder designed for a service life longer than 15 years. This new cylinder was based on ISO 11119, an international design standard. In August 2008, DOT granted Luxfer special permit 14232 (SP14232), which authorizes the manufacture of these cylinders for use in the United States.

While cylinders made under SP14232 are designed for service lives as long as 30 years, the special permit explicitly sets forth certain testing and validation requirements that must be met before the service life of any cylinder may be extended beyond 15 years. As of the issue date of this bulletin, no cylinder manufactured under SP14232 has thus far been approved for a service life longer than 15 years since these cylinders have not yet reached the age at which their service life will be eligible for extension.

For more information, please use the DOT links below or contact Luxfer Gas Cylinders at 951-341-2348.

U.S. Department of Transportation special permits searchDOT-CFFC (Basic requirements for fully-wrapped carbon fiber reinforced aluminum-lined)

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Sustained-load cracking (SLC) in ruptured scuba cylinder made from 6351 aluminum alloy

SLC is a thoroughly researched and well-documented metallurgical phenomenon that occasionally develops in cylinders made from 6351 alloy, as well as in other types of pressure vessels and structural components under stress for sustained periods of time. SLC has occurred in cylinders manufactured by various companies, including Luxfer. Cylinders that have been mechanically damaged, over-filled or otherwise abused are more susceptible to SLC, which is not a manufacturing defect, but a phenomenon inherent in the metal itself.

Research has consistently shown that sustained-load cracks grow very slowly, typically taking eight or more years to grow large enough to cause a cylinder leak or, in extremely rare cases, a rupture. Because SLC growth is so slow, properly trained inspectors have adequate opportunity to detect cracks and remove cylinders from service during normal annual inspections or as part of the DOT-required requalification process every five years. Both Luxfer and DOT have long maintained that proper, diligent inspection by correctly trained personnel is the best way to avoid cylinder-related accidents.

It is important to note that SLC has occurred only in a small number of older cylinders made from 6351 aluminum alloy. Cylinders made from 6061 aluminum alloy, the metal currently used by all U.S. manufacturers, have not exhibited SLC.

Luxfer discontinued use of 6351 alloy in June 1988 and since that time has only manufactured scuba cylinders from Luxfer’s proprietary L6X® formula for 6061 aluminum alloy. Out of more than 40 million cylinders, no Luxfer cylinder made from L6X® (6061) alloy has ever exhibited a sustained-load crack.

For more detailed information about SLC, visit the Luxfer website at www.luxfercylinders.com, click “Support” on the top menu bar, click “Frequently Asked Questions” on the left-hand menu and then click the “Sustained-load Cracking (SLC)” heading. For specific dates when Luxfer switched different cylinder models from 6351 to 6061 alloy, click “Support,” then “Technical Bulletins” and scroll down to Dates when Luxfer changed its aluminum alloy from 6351 to 6061 (posted November 12, 2003).

If you have additional questions, call Luxfer’s toll-free customer service line: 800-764-0366.

1See Department of Transportation: HM-220F, Federal Register, Vol. 71, No. 167, pages 51122-51129.

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Paint removal and repainting of Luxfer all-metal and composite cylinders made from 6061 aluminum alloy (L6X®)

Preparation

All-metal Luxfer 6061 aluminum alloy (L6X®) cylinders1—To remove paint from an all-metal cylinder and prepare the surface for repainting, blast with plastic, glass or other soft media just long enough to remove most of the old paint. Do not blast with sand, steel, grit or aluminum oxide media, which are too abrasive. Heavy or improper blasting with hard or overly abrasive media removes metal as well as paint from the cylinder, which can thin the cylinder wall and make the cylinder unsafe to fill or use. Improper blasting also obliterates stamped markings and damages the outer surface of the cylinder.

Never use corrosive, caustic or acidic paint strippers or solvents to remove paint. Never use burning or torching techniques. Do not use knives or other sharp instruments to remove labels.

Once paint has been removed, use a neutral, mild, water-based detergent to wash the cylinder. Rinse the cylinder well and thoroughly dry it at a metal temperature not exceeding 160 degrees F (70 degrees C). Carefully inspect the cylinder surface for damage and corrosion in accordance with all applicable regulations. If the cylinder passes the inspection, it is ready for repainting.

Composite cylinders—Do not attempt to remove intact old paint from composite cylinders by blasting or any other means that may damage the cylinder exterior. Lightly rub the surface with fine-grit emery paper to prepare it for repainting. If the surface is dirty, clean it with a neutral, mild, water-based detergent, then rinse it well and dry it thoroughly.

Never use corrosive, caustic or acidic paint strippers or solvents to remove paint or to clean composite cylinders. Never use burning or torching techniques. Do not use knives or other sharp instruments to remove labels.

Once the outer surface of the cylinder is clean, inspect it for damage in accordance with all applicable regulations. If the cylinder passes the inspection, it is ready for repainting.

All cylinder types—Do not use the above preparatory processes on the internal surface and thread area of any Luxfer cylinder. Different processes (not covered by this document) should be used to clean threads and internal surfaces.

While preparing a cylinder exterior for painting, take care not to damage the valve connection area or cylinder threads. Do not allow any process materials (e.g., cleaning agents, blast media, grit, etc.) to contaminate the threads and inside of the cylinder.

Painting

All-metal Luxfer 6061 aluminum alloy (L6X®) cylinders—Do not use acidic or caustic paints that may damage the cylinder exterior. You may use any neutral, air-drying or aliphatic, water-based or solvent-based liquid paint that is compatible with aluminum. You may also use neutral, aluminum-compatible powder coatings as long as curing temperatures and exposure times do not exceed those recommended by Luxfer. Please note that different aluminum alloys have different maximum-temperature specifications; for example, for Luxfer 6061-alloy (L6X®) cylinders, the maximum metal temperature must not exceed 350ºF (175ºC). Exposure times at various temperatures vary according to alloy. Please contact Luxfer for time/temperature information about the particular cylinder and alloy that you intend to repaint using powder coatings. Cylinders subjected to temperatures and exposure times exceeding Luxfer recommendations or heated to unknown temperatures must pass hydrostatic tests before being filled or used.

Composite cylinders—Use flame-retardant, air-drying or aliphatic, water-based or solvent-based epoxy or polyurethane liquid paints on Luxfer composite cylinders. Do not heat cylinders to speed up curing or drying of paint. Do not use powder coatings or other coatings that must be heated or baked. Never expose composite cylinders to heat exceeding 180ºF (82ºC).

Do not paint over cylinder labels. Mask labels before painting and make sure that they remain legible. (Note: Color coding cylinders to identify gas contents or usage does not eliminate the regulatory requirement for legible, properly configured labels.)

All cylinder types—Do not allow paint to contaminate the threads, valve connection area or internal surface of any Luxfer cylinder.

1Luxfer markets its proprietary version of 6061 aluminum alloy under the registered trade name L6X

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Politique de Luxfer pour l’extension de la durée de vie des bouteilles bobinées en composite

Luxfer Gas Cylinders reçoit occasionnellement des demandes d’extension de durée de vie pour les bouteilles bobinées en composite de Luxfer.

L’ensemble des bouteilles bobinées en composite de Luxfer a été conçu pour une durée de vie spécifique, généralement limitée à 15 ans. Actuellement, aucune autorisation légale ne nous permet de prolonger la durée de vie de ces bouteilles. En outre, si ces produits enregistrent un niveau de sécurité exemplaire, c’est en partie grâce aux limites réglementant leur durée de vie.

C’est la raison pour laquelle la politique de la société Luxfer Gas Cylinders ne prévoit aucune extension de durée de vie des bouteilles en composite.

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Luxfers Grundsatzerklärung hinsichtlich einer vorgeschlagenen längeren Nutzungsdauer von vollumwickelten Verbundflaschen

Gelegentlich erhält Luxfer Gas Cylinders Anfragen über die Möglichkeit, die Nutzungsdauer seiner vollumwickelten Composite-Flaschen zu verlängern.

Alle vollumwickelten Verbundflaschen von Luxfer sind für eine beschränkte Nutzungsdauer ausgelegt, in den meisten Fällen auf 15 Jahre. Derzeit gibt es keine Ausführungsbestimmungen für die Verlängerung der Nutzungsdauer von solchen Flaschen. Überdies hat die gewerberechtlich vorgeschriebene Beschränkungen der Nutzungsdauer zu der beispiellosen Sicherheit dieser Produkte beigetragen.

Aus diesem Grund besteht Luxfer Gas Cylinders auf seinen Unternehmensgrundsätzen und verlängert die Nutzungsdauer seiner Verbundflaschen nicht.

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Luxfer clarifies difference between bowed and bulged aluminum cylinders

Luxfer Gas Cylinders has received an increasing number of inquiries about the difference between “bowed” and “bulged” aluminum cylinders. The pictures and information below are intended to clarify this important difference.

Bowed Cylinder A bow is a slight curve in the sidewall of an aluminum cylinder (see image above). A fairly common cosmetic feature, a bow is not dangerous and does not affect cylinder performance. A bow is an occasional by-product of the manufacturing process, not a manufacturing defect. Bows occur most often in taller cylinders, including scuba cylinders with a capacity of 80 cubic feet or more. A typical bowed cylinder has one convex side curving slightly outward and an opposite concave side (180° degrees away) curving slightly inward. The curves are long and gradual, covering much of the length of the cylinder sidewall. Most bows are barely discernible with the naked eye, but they sometimes become noticeable when you hold a straight edge against the cylinder wall and rotate the cylinder to reveal both the convex and concave sides. More severely bowed cylinders are sometimes called “banana shaped,” and even these cylinders are safe to use. Infrequently a cylinder will have one straight side and one slightly convex (outward curving) side. Such a condition, called an unparallel sidewall or a plano-convexity, is also a type of bow. It does not affect cylinder performance. Inspectors should be careful not to misidentify the harmless, slightly convex side of a bowed cylinder as a bulge, which is completely different and a very rare condition.A bow is often so subtle that the naked eye has difficulty detecting it. (In the picture above, the bow has been exaggerated somewhat to make it clearly visible.) Using a straight edge will usually reveal convexity and concavity. Bear in mind that the convex (outward curving) side is sometimes more pronounced than the concave side. Do not mistake the convexity of a bow for a bulge! (For more information about bulges, see the following section.)

Bulged CylinderA bulge is an extremely rare, dangerous condition. Bulged cylinders must be immediately condemned and removed from service. Unlike a bow, which is usually slight and sometimes difficult to see, a bulge is generally very pronounced and obvious, even to the naked eye. Bulges occur in cylinders that have been overheated or in cylinders with sidewalls thinned by severe corrosion. There are two basic types of bulges. A long, convex bulge protrudes outward noticeably on one side or around the entire circumference of the cylinder; such a bulge occurs when an entire cylinder has been exposed to high heat. A smaller, “goose-egg-shaped” bulge usually indicates localized overheating, which is the result of “spot annealing.”

If you are uncertain whether a cylinder is bulged, remove it from service and contact Luxfer Customer Service before condemning the cylinder.

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Dates when Luxfer changed its aluminum alloy from 6351 to 6061

Between 1987 and 1988, Luxfer Gas Cylinders discontinued use of 6351 aluminum alloy and began using a proprietary version of 6061 aluminum alloy for all its aluminum cylinder models manufactured in the United States. Listed below are the dates by model number when the transitions to the new alloy occurred. Any current Luxfer models that do not appear on this list were never made from 6351 alloy in the first place and have always been made from Luxfer's proprietary 6061 alloy.

SCUBA

S30, S63 -May 1988

S40 - June 1988

S50, S92 - April 1988

S72, S100 - August 1987

S80 - January 1988

S808 - May1987

SCBA

L7, L8, L13 - September 1987

L13 - May 1988

L15 - January 1989

L26 - February 1988

L45 - November 1987

CO2

C1.2, C1.5 - January 1989

C2 - November 1988

C10 - August 1988

C5 - June 1988

C15 - November 1987

C20, C35 - April 1988

C50 - February 1988

Medical

M9 - January 1988

MD15, ME24 - December 1987

Industrial Gas

N22, N150 - May 1988

N33 - November 1988

N60, N122 - December 1987

N88 - December 1988

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Limited warranty for Australia and New Zealand

Effective: September 1, 2003

A. What the Luxfer Limited Warranty covers:

  1. Luxfer Gas Cylinders warrants that each new aluminum or composite cylinder that it manufactures shall be free of manufacturing and workmanship defects. This warranty provision also covers the external and internal cleanliness and the exterior finish of each new cylinder, which will be judged in accordance with regulatory requirements in the country in which Luxfer manufactured and shipped the cylinder, as well as in accordance with Luxfer quality standards.
  2. Luxfer Gas Cylinders further warrants that its aluminum and composite cylinders will pass each required requalification test for 15 years from the original hydrostatic test date if the cylinder has been properly maintained and used in accordance with Luxfer policies, recommendations, usage guides and product literature, as well as periodic technical bulletins and safety bulletins; this information may be found in the publications cited and on the Luxfer Gas Cylinders website at www.luxfercylinders.com. On an aluminum cylinder, the original hydrostatic test date is the earliest test date stamped on the cylinder crown; on a composite cylinder, the original hydrostatic test date is either stamped on the cylinder neck or printed on a label on the cylinder body.
  3. This warranty covers cylinders manufactured by Luxfer Gas Cylinders on or after September 1, 2003, and does not include valves, regulators or any other devices or equipment manufactured by other companies and attached to or used in conjunction with Luxfer cylinders. This warranty is not retroactive to Luxfer cylinders manufactured before September 1, 2003.
  4. IN NEW ZEALAND ONLY: to the maximum extent permitted by law (including, without limitation, under the Consumer Guarantees Act 1993 (“CGA”) and Fair Trading Act 1986 (“FTA”)), Luxfer Gas Cylinders does not warrant, undertake or make any representations, and disclaims all warranties, undertakings or representations, whatsoever (whether implied or express) other than those expressly set out in this warranty. For the avoidance of doubt, notwithstanding anything in this warranty, nothing in this warranty shall be construed as excluding, limiting or modifying any express or implied condition, warranty, right or remedy conferred by the CGA or FTA to any extent not permitted by law.
  5. IN AUSTRALIA ONLY: the express written warranties described in this limited 15-year warranty operate only to the extent permissible by law.
  6. This warranty is subject to the owner, and all users, of the cylinder complying with each of the requirements or restrictions set out in sections B and C below. In the event of any failure to comply with any such requirement or restriction, this warranty shall immediately be void to the maximum extent permitted by law.

B. Restrictions to this Limited Warranty:

  1. Throughout the entire 15-year warranty period, each cylinder must be visually inspected internally and externally by properly trained and certified inspectors at intervals required by applicable regulations in the country in which the cylinder is being used. All tests and inspections, including (but not limited to) required periodic requalification testing, must be performed at the owner’s expense. The results of each required inspection must be properly documented in accordance with applicable regulations. Cylinder inspections, maintenance and usage must also conform to Luxfer policy requirements and technical recommendations (see applicable policy statements and technical information, based on cylinder type, on the Luxfer Gas Cylinders website at www.luxfercylinders.com).
  2. The cylinder must not be filled beyond its rated working capacity. Without limiting the generality of paragraph 5 above, overfilling the cylinder will immediately void this warranty.
  3. The cylinder must be used only for the specific purpose or service for which it was designed. (For example, medical oxygen cylinders must not be used for scuba diving.) Without limiting the generality of paragraph 5 above, using a Luxfer cylinder for a purpose or service for which it was not designed will immediately void this warranty.
  4. Luxfer reserves the right to retest or reinspect any cylinder returned with the claim that it has failed any type of test or inspection (including but not limited to required periodic requalification testing, hydrostatic retesting, ultrasonic testing, eddy-current testing and/or visual inspection). Luxfer further reserves the right to make the final determination concerning proper disposition of any returned cylinder. Disposition will be made in accordance with all applicable regulations in the country in which the cylinder was being used at the time of inspection.
  5. This non-transferable warranty is valid only for, and is for the sole benefit of, the original owner of each Luxfer cylinder. Proper documentation of ownership, such as a valid warranty card and/or an original purchase receipt, will be required to verify ownership before any warranty claims will be honored.
  6. Cylinders will be replaced only in accordance with published Luxfer policy current at the relevant time (see applicable policy statements, based on cylinder type, at www.luxfercylinders.com). Luxfer Gas Cylinders reserves the right to change policies, including any provisions of this limited warranty, without prior notice.

C. This Limited Warranty does not cover:

  1. Cylinders damaged during shipping and handling.
  2. Cosmetic damages, such as scratches, dents, nicks and abrasions that occur after a new cylinder is removed from its packaging for the first time.
  3. Cylinders involved in accidents and fires.
  4. Cylinders subjected to improper use, improper storage, improper maintenance and/or negligence.
  5. Cylinders subjected to unauthorized repairs and modifications, including (but not limited to) grinding, cutting, sand-blasting, shot-blasting, media-blasting, sanding, brushing, polishing, engraving, scraping and any other activity that removes metal from aluminum cylinders or affects the epoxy resin matrix or protective fiber overwrap on composite cylinders. Additional unauthorized activities include subjecting cylinders to harsh chemicals (e.g., certain cleaners, caustics, acids, solvents, coatings and other corrosive substances); exposing cylinders to heat processes that could anneal aluminum or adversely affect epoxy resin and fibers; recutting or resurfacing O-ring glands; and rethreading cylinders. Without limiting the generality of paragraph 5 above, such unauthorized activities will immediately void this limited warranty. Moreover, cylinders modified or affected by such unauthorized activities may become unsafe to fill and use. Luxfer shall not be responsible or liable for the condition or performance of any Luxfer cylinder modified by unauthorized persons or companies. (See the usage guides and product literature accompanying Luxfer cylinders, as well as technical and safety information published by Luxfer and posted on the Luxfer website at www.luxfercylinders.com.)

D. To obtain warranty service for your Luxfer cylinder:

  1. Contact the Luxfer customer service department in the country in which the cylinder is being used. In Australia & New Zealand please call: 61 2 9830 0999.
  2. Be prepared to provide the following: i) serial number, ii) original hydrostatic test date, iii) description of the problem.

If you have questions about this limited warranty, please call Luxfer Customer Service in Australia at 61 2 9830 0999.

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Transport Canada

Transport Canada reports to Parliament and Canadians through the minister of Transport. It works with its portfolio partners, other government departments and jurisdictions, and industry to ensure that all parts of Canada's transportation system work well.

Transport Canada employs 4,700 people at its headquarters and in five regional offices across the country.

Find out more on their website.

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UK Health and Safety Executive

This has helped make Britain one of the safest places in the world to work, saving thousands of lives, preventing many more injuries at work and reducing the economic and social costs of health and safety failures. Find out more on their website.